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chemical energy with a photosynthetic efficiency

Evolution of the process
Although life and the quality of the atmosphere today depend on photosynthesis, it is likely that green plants evolved long after the first living cells. When Earth was young, electrical storms and solar radiation probably provided the energy for the synthesis of complex molecules from abundant simpler ones, such as water, ammonia, and methane. The first living cells probably evolved from these complex molecules (see life: Production of polymers). For example, the accidental joining (condensation) of the amino acid glycine and the fatty acid acetate may have formed complex organic molecules known as porphyrins. These molecules, in turn, may have evolved further into coloured molecules called pigments—e.g., chlorophylls of green plants, bacteriochlorophyll of photosynthetic bacteria, hemin (the red pigment of blood), and cytochromes, a group of pigment molecules essential in both photosynthesis and cellular respiration.

greenness of plants
greenness of plants
The perfect absorbers of solar radiation are black objects, yet plants, which depend on efficient mechanisms of absorbing solar radiation, are overwhelmingly green. Speculation of why this is so ranges from random chance to the possibility that the radiation-absorbing properties of chlorophyll were adequate to provide for the energy needs of Earth’s plants.
© MinuteEarth (A Britannica Publishing Partner)

Primitive coloured cells then had to evolve mechanisms for using the light energy absorbed by their pigments. At first, the energy may have been used immediately to initiate reactions useful to the cell. As the process for utilization of light energy continued to evolve, however, a larger part of the absorbed light energy probably was stored as chemical energy, to be used to maintain life. Green plants, with their ability to use light energy to convert carbon dioxide and water to carbohydrates and oxygen, are the culmination of this evolutionary process.